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Oil-in-Water Measurement Solutions

Real time industrial measurement and detection solutions for oil-in-water.

DISCUSS SOLUTIONS WITH US

Why Continuously Measure Oil-in-Water?

Monitoring oil contamination in water streams is a challenge across a wide range of industrial processes. Whether originating from petroleum products, lubricants, hydraulic fluids, heat transfer systems, food-grade oils, or process leaks, the presence of oil can impact product quality, wastewater treatment efficiency, equipment reliability, and environmental compliance. While floating oil layers are often visible and relatively easy to detect, dissolved and dispersed oil contamination within the water itself can be far more difficult to identify and quantify. This distinction between oil-on-water and oil-in-water is important, as many process, environmental, and treatment decisions depend on knowing the actual concentration of oil present within the water stream.

Traditional laboratory testing and manual sampling methods provide only periodic snapshots of process conditions and can easily miss short-term contamination events, equipment failures, or sudden process upsets. Real-time, inline measurement provides continuous visibility into changing oil concentrations, enabling operators to respond immediately to developing problems, optimize treatment processes, reduce chemical consumption, and prevent costly environmental incidents. Continuous monitoring also provides valuable process data for troubleshooting, regulatory reporting, and long-term operational improvement.

Oils that contain polyaromatic hydrocarbons (PAHs) naturally fluoresce when exposed to ultraviolet light. By measuring this fluorescence, dissolved and dispersed oil concentrations can be monitored continuously with high sensitivity and selectivity. However, vegetable oils, synthetic oils, and aliphatic hydrocarbons contain little or no aromatic content and therefore cannot be reliably measured using fluorescence alone. To address this challenge, the Kemtrak FL007 combines fluorescence and turbidity measurement technologies in a single analyzer. Fluorescence provides selective detection of aromatic hydrocarbon contamination, while the turbidity channel detects non-soluble, non-fluorescing oils by measuring the cloudiness created by dispersed oil droplets within the water stream.

Together, these complementary measurement techniques provide a versatile solution for monitoring a broad range of oil-in-water applications, from produced water and industrial wastewater treatment to heat exchanger leak detection and utility water protection.

Taking the mystery out of measuring trace oil in water

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Benefits of Continuous Oil-in-Water Measurement

  • Real-time process visibility
  • Early detection of leaks and contamination events
  • Reduced chemical and operating costs
  • Environmental compliance support
  • Reduced risk of permit violations
  • Heat Exchanger Leak Detection
  • Produced Water
  • Industrial Wastewater/Oily Effluent
  • Drinking Water
  • Cooling/Utility Water Protection
  • FAQ's

Heat Exchanger Leak Detection

Heat exchanger failures can allow oils, hydrocarbons, lubricants, and other process fluids to migrate into cooling water, condensate, and utility systems, creating the potential for product contamination/loss, reduced process efficiency, equipment contamination, and unplanned maintenance costs. Even minor leaks can have significant operational and economic consequences if left undetected.

Continuous oil-in-water monitoring provides early warning of developing heat exchanger leaks, enabling operators to identify contamination events as they occur and take corrective action before they escalate into major process disruptions. Real-time monitoring helps protect critical equipment, maintain system performance, reduce downtime, and support predictive maintenance strategies.

Typical applications include refinery heat exchangers, petrochemical process equipment, power plant condensate systems, compressor cooling systems, hydraulic oil cooling circuits, and a wide range of industrial utility networks where early leak detection is essential for reliable operation.

Leak Detection Application Note
FL007 Fluorescence Analyzer

Produced Water and Hydrocarbon Wastewater

Produced water and process wastewater generated throughout the oil and gas value chain often contain residual hydrocarbons, including crude oil, condensate, diesel fuel, and other petroleum products. Real-time oil-in-water monitoring enables continuous assessment of separator performance and treatment system efficiency, providing immediate feedback on process conditions. This allows operators to optimize treatment processes, reduce chemical and operating costs, maximize plant uptime, and maintain compliance with increasingly stringent discharge requirements.

Oil-in-Water Analyzer LITERATURE
FL007 Fluorescence Analyzer

Industrial Wastewater and Oily Effluent Monitoring

Industrial wastewater streams often contain a wide range of hydrocarbon contaminants, including lubricating oils, hydraulic fluids, cutting oils, fuels, and other process-related oils. Continuous oil-in-water monitoring provides real-time visibility into wastewater quality, enabling operators to rapidly detect spills, leaks, and process upsets before they impact treatment efficiency, increase operating costs, or create environmental compliance risks.

By delivering immediate feedback on changing contamination levels, online monitoring helps optimize treatment performance, reduce maintenance requirements, and support regulatory compliance across a broad range of industries, including manufacturing, metal processing, transportation facilities, mining operations, chemical processing, and power generation.

Advanced dual fluorescence and turbidity measurement technology enables the detection of both aromatic petroleum-based hydrocarbons and non-aromatic oil contaminants using a single analyzer platform, providing comprehensive monitoring capability for diverse industrial wastewater applications.

OIL-IN-WATER ANALYZER LITERATURE
FL007 Fluorescence Analyzer

Drinking Water Purity

Detecting oil contamination in drinking water is essential for protecting public health and maintaining access to safe, clean water. Even small amounts of oil can compromise water quality and pose potential health risks to consumers.

Oil contamination can also result in significant economic costs, including extensive cleanup operations, environmental remediation, and infrastructure upgrades needed to prevent future occurrences.

Implementing reliable oil detection systems enables rapid identification and response to contamination events. Early detection helps minimize risks, maintain water quality, reduce costs, and ensure the continued safety and well-being of communities.

OIL-IN-WATER ANALYZER LITERATURE
FL007 Fluorescence Analyzer

Cooling Water and Utility Water Protection

Cooling water and utility water systems often provide the earliest indication of process contamination, making them strategic monitoring points for protecting critical plant infrastructure. The presence of oil or hydrocarbons in a cooling loop can signal seal failures, heat exchanger leaks, lubrication system malfunctions, or other developing equipment issues that may otherwise go unnoticed until significant damage has occurred.

Continuous oil-in-water monitoring delivers real-time protection for these essential utility systems by providing immediate detection of contamination events. Early warning enables operators to respond quickly, helping to prevent fouling, corrosion, equipment damage, treatment system overloads, and costly unplanned downtime. The result is improved asset protection, enhanced operational reliability, and reduced maintenance costs across the facility.

OIL-IN-WATER ANALYZER LITERATURE
FL007 Fluorescence Analyzer

Frequently Asked Questions

What is fluorescence?Expand

Fluorescence occurs when the electrons in a fluorophore release their absorbed energy. Electrons start at ground state (S0) - the lowest energy state available to them. When one collides with a photon, the electron absorbs the photon's energy and jumps up to a higher energy state (S1, S2, etc.). In order to return to ground state, the additional energy absorbed by the electron must be released. This is done via photon emission. The energy of this emitted photon is lower than the energy of the original (colliding) photon, so it has a longer wavelength. This longer wavelength is the cause of a change in color between excitation and emitted lights.

Fluorescence

One substance that exhibits fluorescence is Fluorescein. Fluorescein is a powdered orange dye that, when in solution, exhibits a yellow-green glow when excited by light at a wavelength of around 498nm.

Oils

Aromatic oils are typical example materials that fluoresce. When excited with UV light, fluorescence occurs and this emitted light can be used in the measurement of trace oil-in-water and hydrocarbon contamination monitors.

How does the Kemtrak FL007 detect oil in water?Expand

The FL007 uses ultraviolet (UV) fluorescence to detect aromatic hydrocarbons in water. When aromatic oil molecules absorb UV light, they emit light at a longer wavelength. The intensity of this fluorescence is proportional to the concentration of oil present, allowing continuous real-time monitoring of dissolved and dispersed oil contamination.

Fluorescence intensity is unique to each oil type. Exciting the oil with ultraviolet (UV) radiation causes it to fluoresce in the UV-visible wavelength range, as shown in the diagram below.

Oil Fluorescence

What is the ideal sensor configuration for measuring fluorescent oils?Expand

Because fluorescence energy is emitted in all directions from poly-aromatic molecules, the simplest measurement method is to use a single optical window arrangement through which both excitation and emitted light passes.

sensor configuration

Emitted light intensity is very low in comparison to excitation light intensity. To combat this, the use of a fiber optic cable to deliver the excitation light and a fiber optic bundle to collect emitted light allows for better signal levels and creates a more reliable measurement.

Key features of an oil-in-water fluorescence sensor are:

  • Probe style with a single window format
  • Large gathering area for emitted energy to improve signal levels and measurement reliability
What types of oils can be measured using fluorescence?Expand

Fluorescence works for oils containing aromatic hydrocarbons, such as crude oil, fuel oil, hydraulic oil, transformer oil, and many petroleum-based products. Since each oil has a unique aromatic content, the fluorescence response varies by oil type. Calibration should be based on the specific oil being monitored.

Why does the FL007 combine fluorescence and turbidity measurements?Expand

No single measurement technology can reliably detect all oil types. Aromatic oils produce a fluorescence signal, while non-aromatic or low-aromatic oils may not fluoresce significantly. The FL007 simultaneously measures turbidity to detect oil droplets and other hydrocarbon contamination that may not generate a strong fluorescence response, providing higher measurement confidence and broader oil coverage.

Do suspended solids, bubbles, or entrained gas affect the fluorescence measurement?Expand

No. Solids and gas bubbles do not fluoresce and therefore do not directly interfere with the fluorescence channel. This gives fluorescence-based oil-in-water measurement a significant advantage over many alternative technologies that can be affected by suspended particles or air entrainment.

Why is site-specific calibration important?Expand

Different oils contain different concentrations of polyaromatic hydrocarbons (PAHs) and therefore produce different fluorescence intensities. For the most accurate oil concentration measurement, the FL007 should be calibrated using samples of the actual oil and water mixture found in the process. The analyzer can store multiple calibration curves for different oil types/operating conditions.

What applications are best suited for a fluorescence-based oil-in-water analyzer?Expand

The FL007 is commonly used for heat exchanger leak detection, cooling water monitoring, condensate return systems, produced water treatment, wastewater discharge monitoring, environmental compliance, drinking water protection, and early detection of lubricant contamination in industrial processes. Continuous online monitoring allows operators to detect leaks and contamination events immediately rather than waiting for laboratory test results.

Have more questions? Take a quick moment to get in touch with our expert sales engineers and technologists and we'll guide you to a solution.

SOUTH FORK INSTRUMENTS IS COMMITTED TO SOLVING YOUR FACTORY AND PROCESS AUTOMATION CHALLENGES

Why Choose South Fork Instruments?
We’re both a supplier of pH measurement solutions and a partner in your production success. Our inline pH sensors and controllers are assembled with your specific needs in mind. Contact us today to explore how our pH solutions can transform your operations.

TALK TO OUR EXPERTS

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